Does Ferric Hydroxide - Fe(OH)3 exist and why does OLI model it?

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A question was raised by a user:

I have always questions, probably because my knowledge of inorganic chemistry is superficial. I read in the book "De la solution à l'oxyde" by Jean-Pierre Jolivet (2015), "Fe(OH)3 does not exist". The same thing is written in "Metal Oxide Chemistry and Synthesis: From Solution to Solid State", which seems to be the english version of same book. I find also the same sentence in "Proceedings - Soil Science Society of America", all these sources say that various forms of ferrihydrite FeOOH is generated by precipitation but not Fe(OH)3."


OLI Systems' response (user: pwang : Peiming Wang)