Difference between revisions of "MSE Density Parameter Update"
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Standard state chemical potentials in the two normalizations are related by | Standard state chemical potentials in the two normalizations are related by | ||
[[File:T9.jpg]] (or [[File:T10.jpg]]) | [[File:T9.jpg]] (or [[File:T10.jpg]]) | ||
| − | which is derived from equality of chemical potentials in two normalizations, and using [[File:T11.jpg]] | + | which is derived from equality of chemical potentials in two normalizations, and using [[File:T11.jpg]]1 in the infinite dilution limit. Derivatives of ’s with respect to pressure give volumes, i.e. |
Revision as of 06:55, 11 July 2016
In UNIQUAC term, the excess molar volume,
, is assumed to be analogous to that of the excess Gibbs energy, i.e.
(Combinatorial term omitted)
where 
is a different interaction parameter from that of 
in the 
model.
The symmetrically normalized 
(subscript UNIQ is omitted in the following text) needs to be converted to the unsymmetrically normalized value (
) for density calculations in MSE.
Conversion fromto :
Standard state chemical potentials in the two normalizations are related by
(or 
)
which is derived from equality of chemical potentials in two normalizations, and using 
1 in the infinite dilution limit. Derivatives of ’s with respect to pressure give volumes, i.e.
